Control of Spots and Stains on the Surface of Cold-Rolled Thin Sheets
Among steel products, cold-rolled sheets have very strict requirements for surface quality. Surface defects are the most significant quality issues for cold-rolled sheets. Once surface defects occur in cold-rolled sheets, they will seriously affect the quality and performance of subsequent deep-processed products. For a period of time, the cold-rolled products of the First Steel Rolling Plant of Maanshan Iron & Steel Co., Ltd. were plagued by surface spot defects, which had a very adverse impact on the image of the products of the First Steel Rolling Plant and even Maanshan Iron & Steel Co., Ltd. in the market, and caused huge economic losses. From June 2011 to April 2012, the cold-rolled products of the First Steel Rolling Plant paid compensation for 21,417 tons due to quality issues, among which surface spot defect quality issues accounted for nearly one-third of the total quality issues, becoming an urgent problem to be solved.
The cold-rolled steel sheets of Ma Steel have irregular spots, patches and streaks on their surfaces. The lighter ones are light yellow, while the more severe ones are brownish-yellow or red. In the most serious cases, they are dark brown and the surfaces are rough. Maanshan Iron & Steel Co., Ltd. collaborated with the School of Science of Naval University of Engineering to analyze the factors causing the spots on the cold-rolled products. Firstly, they ruled out the possibility of small steel coils blocking the base due to improper stacking and centering during loading and furnace entry, which led to blackening of the steel coils after annealing and the inability to remove residual carbon on the surface. They also excluded the possibility of surface rust caused by rain leakage in the warehouse or water droplets from air conditioners falling on the steel coils during crane movement, as well as uneven oil application in the oiling system. Then, they conducted a deeper analysis of the influencing factors.
They found that the majority of the spot defects occurred in the products of the flattening line, and reducing the output of the flattening line products and changing them to be produced by the finishing line could significantly reduce the occurrence of such defects. Among them, the flattening blow-off system and the flattening liquid system were closely related to the occurrence of surface spot defects.
- The influence of flattening liquid pH value on spots
Both acidic and alkaline liquids have a corrosive effect on the surface of the steel sheet, easily forming fine point-like corrosion pits on the surface and accumulating in the pits to cause oxidation reactions and form spots. Experiments show that when the pH value is between 7 and 9, there is no correlation between the pH value and the occurrence of spots. Therefore, the pH value of the flattening liquid is set to be between 7 and 9. - The influence of flattening liquid concentration on spots
The flattening liquid comes into direct contact with the surface of the steel strip, with the aim of lubricating the steel coil rolling process. Experiments show that the concentration of the flattening liquid has a significant impact on spots. At a concentration of 2.4%, spots occur 100% of the time; at concentrations of 2.94%, 3.36%, 3.77%, and 4%, no spots occur. Based on the experimental results and cost considerations, the concentration of the flattening liquid is set to be greater than 2.4% and less than or equal to 4% as the operating standard. - The influence of dynamic blow-off pressure of flattening liquid on spots
The experimental results show that when the dynamic blow-off pressure of the flattening liquid is maintained at 5 kg or above, it has no effect on spots. Therefore, it is stipulated that the dynamic blow-off pressure of the flattening liquid must be maintained at 5 kg or above, and the machine should be shut down if it is below this standard value. - The influence of the temperature of the flattening liquid mixing tank on spots
The experimental results show that the temperature of the flattening liquid mixing tank is closely related to the occurrence of flattening liquid spots. When the temperature is above 50°C, the number of spotted coils is the least, and when it is below 30°C, the number of spotted coils is the most. Therefore, it is stipulated that the temperature of the flattening liquid mixing tank should be controlled above 50°C.
Based on the experimental and analytical results, Ma Steel took corresponding measures, and the quality disputes caused by surface spot defects were significantly reduced, achieving excellent results, equivalent to an indirect increase in efficiency of 79,200 yuan per month.
